Recycled Materials, Green Chemistry and the Circular Economy

Recycled Materials, Green Chemistry and the Circular Economy

Analytical and Testing Instruments to Support Green Chemistry

The goal of a circular economy is to reduce waste and pollution by harvesting materials from renewable sources and reusing materials through recycling, repurposing, and reprocessing. Shimadzu instruments are used by leading scientists worldwide to develop new materials and manufacturing processes that both enhance product performance and reduce harmful environmental impacts in all phases of the circular economy from basic chemical characterization of raw materials and waste streams to the measurement of novel material properties.

Commonly recycled plastics, such as polyethylene, polypropylene, polystyrene, and polyethylene terephthalate, are subject to quality standards to verify their composition and prevent contamination of recycling streams. This can be achieved using analytical instrumentation such at Fourier-Transform Infrared Spectroscopy (FTIR) and Energy Dispersive X-Ray Fluorescence (EDX). Harvesting materials and fuels from waste and renewable sources requires extensive testing to monitor processing steps and ensure purity using, for instance, gas chromatography (GC), liquid chromatography (LC), or elemental analysis.

Renewable materials are also being explored for the creation of bio-based materials and composites with properties that are comparable to plastics created from petroleum. Their physical properties can be evaluated using Shimadzu’s AGX-V universal test machines, thermal instrumentation, and surface analysis. Raw materials derived from hemp are an example where natural products may replace many synthetically manufactured materials. Nanocellulose, a form of defibrated cellulose derived from plant matter, is another material being researched as an environmentally renewable biomaterial with desirable properties, including high strength, thermal stability, and gas-barrier properties.

 

Shimadzu’s Commitment to the Environment

As a long-standing member of the Japan Association for Chemical Innovation (JACI), Shimadzu Corporation is at the vanguard of the international green Chemistry movement. Shimadzu also constantly strives to reduce its environmental impact through various initiatives to reduce waste and energy consumption.

Featured Applications

Industrial Hemp Brochure

Complete Solutions for the Industrial Hemp Market:
Flower, Stalk, Seed, Leaves & Root

Hemp in the United States and worldwide is a hot topic because of its green nature, sustainability, and zero or low carbon footprint. While it appears most of the hemp world has been flower-centric on the health benefits of cannabinoids and terpenes, this is only the tip of the iceberg with respect to applications. The entire plant, including flower, seed, stalk, leaves and root, has 50,000 different uses.

This communication will present a limited number of the potential 50,000 different uses. However, Shimadzu is the only worldwide company able to provide analytical instruments, physical testing machines, and X-ray equipment for complete profiling of the hemp plant from development to the final product.

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Solutions for Cellulose Nanofibers Brochure

Solutions for Cellulose Nanofibers

As a consultant for comprehensive analysis of CNF, Shimadzu aim to support research and development to expand the use of CNF. By developing cutting-edge technologies, Shimadzu provides solutions for detailed analysis of CNF properties such as optical transmittance morphology, dispersibility, and different surface functional groups. These analyses are further explored in this booklet comprehensively to help you better investigate and characterize nanocellulose materials. These efforts will help accumulate more experimental, theoretical and analytical data, fostering collaborations to help advance this field forward for practical applications in the near future. Shimadzu will help realize dreams for the next generations with the well-being of mankind and the Earth.

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Quantitative Analysis of Recycled Plastics Using FTIR – Mixing Ratio Calculation Method

IRAffinity-1S Fourier Transform Infrared (FTIR) Spectrophotometer

The main four components of recycled plastics are polyethylene (PE), polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET), which are all commodity resins. Quality standards are defined for recycled plastics and to determine the composition of components, generally a sample is dissolved in a solvent and then analyzed using a nuclear magnetic resonance (NMR) spectrometer. In place of this general method, this article introduces a screening analysis method using a Fourier transform infrared spectrophotometer (FTIR). Quantitation is possible by either the individual calculation method, in which the concentration of each component is calculated individually, or the mixing ratio calculation method, in which the concentration of each component is calculated by taking the sample as a whole as 100 %. This article studies the mixing ratio calculation method. A major feature of this method is that unlike the precision analysis using an NMR spectrometer, sample pretreatment is unnecessary and therefore speedy calculations of the composition of components are possible.

Download Application (PDF)  Learn more about the IRAffinity-1S 

 

Analysis of Polycarbonate Using a Benchtop MALDI-TOF Mass Spectrometer

MALDI-8020 Benchtop Linear MALDI-TOF Mass Spectrometer

In recent years, recycling related laws have been enforced for the purpose of global environmental preservation, which in turn has increased the amount of recycled plastic products around us. This trend entails the needs of rapid and detailed analyses of recycled products. In such cases, sufficient information may be obtained by analyzing not the entire polymers but oligomers. Conventionally, oligomers are analyzed by combining rough separation using the dissolution/reprecipitation method, etc., and various chromatographic or spectroscopic techniques. On the other hand, recently MALDI-TOF mass spectrometers are extensively used for oligomer analysis. By using such instruments, the information of terminal groups and monomer units can be obtained rapidly. This article introduces an example analysis of polycarbonate, which was performed by combining rough separation of oligomers by the dissolution/reprecipitation method and measurement and analysis using the benchtop MALDI-TOF mass spectrometer "MALDI-8020".

Download Application (PDF)  Learn more about our Benchtop MALDI-8020 

 

Toward Recycling of Marine Debris - Analysis of Microplastics Using FTIR and EDX

IRTracer-100 and EDX-8000

The causes of deterioration and breakup of fishing nets are contact with fish, algae, and stones in the sea and on beaches, as well as ultraviolet radiation from the sun. An example of a way to prevent this kind of naturally occurring damage and continue using fishing nets over a long period of time is to give the surface of fishing nets used for aquaculture a protective coating of copper as shown in Fig. 2 (1). Fig. 2 Fishing Net Used for Aquaculture The heavy element copper (Cu) used for the protective coating has an antibacterial effect and not only protects against bacteria and viruses but also has the function of preventing fouling, so it plays an important role on fishing nets. Copper not only maintains the strength of the fishing nets, but also gives excellent functionality. However, in recent years it has been reported that it might have a negative impact on fish and the marine environment, and its use has been a concern. This article introduces an example of analysis using FTIR and EDX on actual fishing nets collected on the Playa de Muro beach on the Spanish island of Majorca and the Paal 9 beach on the island of Texel in the Netherlands, and on fishing nets obtained from a recycling plant.

Download Application (PDF)  Learn more about the IRTracer-100  Learn more about the EDX-8000 

Shimadzu's Environmental Initiatives

Bioplastic Packaging Materials

Shimadzu is continuously improving energy efficiency and making all our products more compact to minimize the environmental impact throughout the entire product life cycle. At the same time, we actively procure parts and materials that reduce the environmental impact of packaging and other secondary materials.

Certified “Eco-Products Plus” Models are Smaller, More Energy Efficient, or Offer Other Superior Environmental Performance

Shimadzu offers “Eco-Products Plus” certified products that achieve an exceptionally high environmental performance. Specifically, “Eco-Products Plus” models are certified by Shimadzu to achieve at least a 25 % reduction in power consumption, size, and/or consumables usage compared to the previous model.

For the Earth, For the Future – Environmental Analytical and Measuring Instruments

Rapid global economic and societal growth and development have resulted in problems with large storms, flooding, and other natural disasters from climate change and problems with environmental pollution from large quantities of waste and hazardous substances. At Shimadzu, in an effort to help solve environmental challenges and achieve sustainable development goals, we contribute to establishing a sustainable society by offering a wide variety of instruments and services for analyzing and measuring the environment.

Plastic, Recycling and Environmental aspects Interview with Albert van Oyen Managing Director from CARAT GmbH

Modern plastics are highly regulated, especially food packaging. The problem for plastic recyclates is even greater; these are complex mixtures from the past that have to meet modern requirements. For identification and contaminant analyses, FTIR-ATR is a helpful tool. Element analyses (EDX and ICPE) help us to qualify and quantify possible additives (heavy metals) from the past. Mechanical property evaluations with the Autograph also provide important information as part of this component analysis, contributing to the effective reuse of plastics.

Journals & Papers

Shimadzu Journal - Material Science and more...

Shimadzu Journal - Material Science and more...

This issue focuses on Material Science and contains results from two collaborations. One is with Professor Frank Walther of TU Dortmund University in Germany and the other with the Japan Aerospace Exploration Agency (JAXA). Both use our testing machines and analytical instruments. IN addition, this issue contains information on other applicable topics, as well as the latest news and applications.

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Towards the Use of Novel Materials in Shipbuilding: Assessing Thermal Performances of Fire-Doors by Self-Consistent Numerical Modelling

Kyaw Oo D’Amore, G.; Mauro, F.; Marinò, A.; Caniato, M.; Kašpar, J. Towards the Use of Novel Materials in Shipbuilding: Assessing Thermal Performances of Fire-Doors by Self-Consistent Numerical Modelling. Appl. Sci. 202010, 5736.

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Improving Dispersion of Recycled Discontinuous Carbon Fibres to Increase Fibre Throughput in the HiPerDiF Process

Pozegic, T.R.; Huntley, S.; Longana, M.L.; He, S.; Bandara, R.M.I.; King, S.G.; Hamerton, I. Improving Dispersion of Recycled Discontinuous Carbon Fibres to Increase Fibre Throughput in the HiPerDiF Process. Materials 202013, 1544.

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Analysis of Mechanical Properties of Unidirectional Flax Roving and Sateen Weave Woven Fabric-Reinforced Composites

Lemmi, T.Sh., Barburski, M., & Samuel, B. T. (2020). Analysis of Mechanical Properties of Unidirectional Flax Roving and Sateen Weave Woven Fabric-Reinforced Composites, Autex Research Journal (published online ahead of print 2020). doi: https://doi.org/10.2478/aut-2020-0001

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Mercerization Optimization of Bamboo (Bambusa vulgaris) Fiber-Reinforced Epoxy Composite Structures Using a Box–Behnken Design

Hassan, M.Z.; Roslan, S.A.; Sapuan, S.M.; Rasid, Z.A.; Mohd Nor, A.F.; Md Daud, M.Y.; Dolah, R.; Mohamed Yusoff, M.Z. Mercerization Optimization of Bamboo (Bambusa vulgaris) Fiber-Reinforced Epoxy Composite Structures Using a Box–Behnken Design. Polymers 202012, 1367.

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A novel sandwich panel made of prepreg flax skins and bamboo core

L ́ıvia ́Avila de Oliveira ,Gabriela Luiza Cota Coura ,Maikson Luiz PassaiaTonatto ,   T ́ulio Hallak Panzera ,   Vincent Placet ,   Fabrizio Scarpa ,  A  novelsandwich  panel  made  of  prepreg  flax  skins  and  bamboo  core,Composites  Part  C:  Open  Access(2020), doi: https://doi.org/10.1016/j.jcomc.2020.100048

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